Bouboulina was born in Constantinople in 1771. Her father was Stavrianos Pinotsis, an Arvanite from Hydra and her mother was Skevo Kokkini, descendant of the Byzantine Kokkinis family. During her youth, she developed an interest in sailing which was facilitated by her stepfather’s liberal attitude to education. She was widowed twice, inheriting a considerable sum of money from her second husband. She later allegedly joined the Filiki Etaireia secret society which sought to achieve Greek independence from the Ottoman Empire, being among the few women to do so. Following the outbreak of the Greek War of Independence she commanded a fleet of Spetsiot ships which contributed to several campaigns most notably the siege of Nafplion. Following the defeat of her faction in the Greek civil war in 1824, Bouboulina was briefly imprisoned and expelled to Spetses. She was killed on 22 May 1825, during the course of a family feud.